Short script to copy group membership from one account to another.

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$CopyFromUser = Get-ADUser user1 -prop MemberOf
$CopyToUser = Get-ADUser user2 -prop MemberOf

$CopyFromUser.MemberOf |
    Where-Object {$CopyToUser.MemberOf -notcontains $_} |  
    Add-ADGroupMember -Members $CopyToUser
Categories: Powershell